| Satista+
A combined silver palladium and/or platinum process
The traditional Satista process was
an economical hybrid of platinum and silver. The problem with combining
these two metals is that the silver compound is in a nitrate form
(one of the few common soluble compounds of silver) and the palladium
is in the form of a chlorine compound. Silver nitrate immediately
converts to insoluble silver chloride when mixed with a chlorine
compound, thus the two cannot be combined in the emulsion. In order
to get these two basically incompatible compounds to mix the traditional
Satista process involved developing a pre-coated paper called Satista
containing the ferric oxalate and the platinum or palladium chloride
compounds in a developer of silver nitrate. Having a tray of silver
nitrate around is messy (stains hands and everything else it touches)
expensive, and prone to getting grungy due to iron and other things
going in during development. For this reason the process has not
enjoyed much modern usage.
With the price of palladium now in the
$900.00 per ounce range (December 2000) a more economical pt/pd
process might be welcome.
This new process I call Satista+ was
inspired by my Extravagatype process where glycerin restrained the
developer. (See The New Platinum Print by Sullivan and Weese)
This process is at the moment considered
EXPERIMENTAL! Not a whole lot of the details have been worked out
and I am sure it is ripe for modification, especially by this rag-tag
group of alt-photo miscreants!
Please don't bug the B+S staff for any
help or they'll lock me in the paint locker out back again for 2
or 3 days where I get to watch continuous re-runs of Papillion through-out
the ordeal. Email me direct for help.
In a nutshell:
For an 8x10 print
Make an emulsion of:
25 drops of ammonium ferric oxalate
3 drops of Potassium chloroplatinite Pt Std No 3.
- or -
3 drops of sodium palladium chloride No 3.
Dry as you would an ordinary pt or pd
print. It must be very dry as the AFO will cause an unwanted print-out
Expose under a negative in the ordinary
manner
Tape the exposed print down on a piece
of window glass about 2 or three inches larger all around than the
print
Develop in:
10 ml glycerin
2 ml Silver nitrate 10 % Solution
Spread the developer on the print with brush or rod. This can take
up to 5 minutes if it is cold.
The print will turn black and messy looking
but the mess should wash off completely.
Wash and fix in a very dilute sodium thiosulfate
solution. (5 gm per Liter H2O)
Clear in EDTA or your favorite clearing agent
as you would a pt/pd print
Comments
The prints I have made are indistinguishable in looks from ordinary
Pd prints developed in potassium oxalate.
They will bleach out in nitric acid whilst
pd+pt prints will not.
They will not bleach out in the fix like Kallitypes.
The process seems to be much tamer than the
traditional Kallitype process which has a tendency to go out of
whack and disappear in the fix.
As you are using only 3 drops of the expensive
metal in the emulsion cost is considerably less than that of the
traditional pd print.
Reducing or increasing the noble metal beyond
the 3 drops changes color.
Less silver nitrate may be used.
Glycerin can be obtained from your local drug
store (chemist to you Brits!) We also sell it.
The pd and pt solutions are the same as used
in standard pt or pd printing.
Dilute Kodak fixer works.
There were numerous complaints in the olden
days about folks entering Kallitypes into competition and calling
them platinums! Tsk Tsk! I can see these masquerading as pd/pt prints
as well.
Forum for help and comments is at the B+S discussion
group at:
http://sirius.secureforum.com:8080/~bostick/login
The discussion group is both free and commercial free and spam free.
--Dick Sullivan |